Transistor Scaling Requires New Materials

The industry has made enormous investments to achieve multiple generations of FinFET scaling. As we enter the single-digit-nanometer regime, however, electrical resistance in the contact and interconnect is negating the area/cost advantages of further transistor scaling.

Specifically, at ever more critical dimensions, tungsten transistor contacts and copper local interconnects are hitting the wall. Continued 2D scaling depends on identifying and successfully integrating new materials that can deliver low power and high performance. Such materials are critical to improving on-current, reducing delay and managing dynamic leakage—enabling power-performance improvements, node after node.

The Promise of Cobalt

Cobalt promises lower resistance at smaller geometries, in part due to the metal’s inherent characteristics when compared to tungsten and copper at small dimensions, and in part because cobalt works with thinner barriers, which allow for sufficient volume to be maintained.

Integrating cobalt is not trivial, but Applied Materials has developed an “Integrated Materials Solution” for cobalt whereby the multiple process chambers needed to integrate cobalt can be combined into the same Endura platform, allowing wafers to be kept in vacuum for pristine materials engineering at ever more critical dimensions.

Reengineering the Transistor Contact and Local Interconnect

Tungsten has been the material of choice for contact metallization due to its ease of integration and reliability. But, we’ve reached the point where it presents a scaling bottleneck. This is because the thickness of the ALD titanium nitride barrier layer that tungsten requires to protect the underlying titanium layer doesn’t scale in proportion with the reduction in critical dimensions (CDs). The result is increased contact resistance and decreased on-state current.

Replacing the tungsten contact and local interconnect with cobalt removes this scaling bottleneck. The interest in cobalt as a new material of choice is driven by the fact that it has bulk resistivity similar to tungsten, yet is about 1.5-2x less resistive due to impurities and grain boundary scattering in tungsten. Other advantages are that CVD cobalt allows a thinner titanium nitride layer and a seamless fill compared to CVD tungsten (Fig. 2).

The industry has already begun using cobalt to reduce contact and middle of line resistance. Replacing tungsten contacts with cobalt has paid dividends with an approximate 60 percent improvement in contact line resistance. Replacing the short-length copper interconnect at the lowest metal contact layers with cobalt has reduced via resistance (for lower IR drop) and improved electromigration reliability.^[1] To speed customer adoption, Applied has developed a robust Integrated Materials Solution for reliably engineering cobalt contacts and lower-level interconnects.

What is the Future of Copper Interconnects?

Given the advantages of cobalt, the question many ask is why not use it to replace copper in more of the interconnect layers? A detailed analysis of line resistance scaling shows that copper is superior or adequate to CDs of 12-15nm. For metal levels above M1, where the interconnect is long enough for line resistance to be the key performance factor, copper wins.

Copper Extension Continues

There is strong industry incentive to extend copper as far as possible. As discussed, while via resistance is optimized by reducing barrier thickness, line resistance is about maximizing the volume of copper by thinning both the barrier and liner. All of this needs to be accomplished while maintaining perfect metal fill and high reliability.

New, integrated and co-optimized technologies are needed to extend copper (Fig. 3). These include replacing the PVD tantalum nitride barrier with ALD tantalum nitride and using copper reflow on cobalt liners for the fill. The ALD barrier approach provides a path to scale copper below 36nm pitch. Beyond this, selective via fill schemes promise lower via resistance by eliminating high-resistivity barriers, providing new options for addressing interface management issues.

Beyond Copper and Cobalt

Filling smaller interconnects is becoming more difficult, and reliability can suffer. New conductor materials and different metallization schemes and technologies are needed to solve challenges over the long term. The issue goes beyond identifying metals with lower theoretical resistivity: we also need to explore the needs for barriers and liners. We need to determine whether the ever-smaller volumes can be successfully filled, and whether the process can be successfully integrated. The materials engineering challenges include managing the materials interfaces to improve reliability and co-optimizing the barrier-liner-fill to optimize resistance, yield, cost and reliability.

New materials of interest include ruthenium and molybdenum, but both still lag cobalt from a maturity perspective.

Longer Term Solutions

Over the next two to three nodes, the focus will be on extending copper interconnects as long as possible while pioneering the best candidates to eventually replace copper. Looking beyond the horizon, fundamental changes loom. Subtractive etch schemes may help overcome the challenges associated with the damascene approach—but they are in the very early stages of exploration. While promising, such changes represent a seismic shift for the industry, requiring entirely new technology portfolios. As we look to the future of interconnect technology, we foresee numerous issues related to defectivity, yield and reliability issues. Integrated Materials Solutions give us new ways to address etching more exotic metals, filling ever-smaller gaps and self-aligning critical features.

In summary, logic scaling can continue as long as we can also find and successfully integrate promising new materials that allow “PP” to scale with “AC.” The industry needs to accelerate materials innovation, and Applied is delivering Integrated Materials Solutions that can speed customer success.

^[1] C. Auth et al, “A 10nm high performance and low power CMOS technology featuring 3rd generation FinFET transistors, self-aligned quad patterning, contact over active gate and cobalt local interconnects,” 2018 IEEE International Electron Devices Meeting (IEDM), San Francisco, CA 

Tags: interconnects, Cobalt, copper, contacts, ALD